莨菪烷

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{{chembox | verifiedrevid = 444238033 | Reference =<ref>''Merck Index'', 11th Edition, '''9689'''.</ref> | ImageFileL1 = Tropane svg.svg | ImageSizeL1 = 150px | ImageFileR1 = Tropane-3D-sticks.png | ImageSizeR1 = 150px | IUPACName = ''N''-Methyl-8-azabicyclo[3.2.1]octane | OtherNames = 2,3-Dihydro-8-methylnortropidine | Section1 = {{Chembox Identifiers | Abbreviations = | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 553556 | InChI = 1S/C8H15N/c1-9-7-3-2-4-8(9)6-5-7/h7-8H,2-6H2,1H3/t7-,8+ | InChIKey = XLRPYZSEQKXZAA-OCAPTIKFBA | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C8H15N/c1-9-7-3-2-4-8(9)6-5-7/h7-8H,2-6H2,1H3/t7-,8+ | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = XLRPYZSEQKXZAA-OCAPTIKFSA-N | InChIKey1 = XLRPYZSEQKXZAA-OCAPTIKFSA-N | CASNo = 529-17-9 | EINECS = | PubChem = 637986 | SMILES = N1(C)[C@H]2CC[C@@H]1CCC2 | InChI = | RTECS = | MeSHName = | ChEBI_Ref = {{ebicite|correct|EBI}} | ChEBI = 35615 | KEGG_Ref = {{keggcite|correct|kegg}} | KEGG = | ATCCode_prefix = | ATCCode_suffix = | ATC_Supplemental =}} | Section2 = {{Chembox Properties | Formula = C₈H₁₅N | MolarMass = 125.211 g/mol | Appearance = | Density = 0.9259 at 15 °C | MeltingPt = | Melting_notes = | BoilingPt = 163-169 °C | Boiling_notes = | Solubility = | SolubleOther = | Solvent = | pKa = | pKb = }} | Section7 = {{Chembox Hazards | EUClass = | EUIndex = | MainHazards = | NFPA-H = | NFPA-F = | NFPA-R = | NFPA-O = | RPhrases = | SPhrases = | RSPhrases = | FlashPt = | Autoignition = | ExploLimits = | PEL = }} }} '''莨菪烷'''（{{lang-en|'''Tropane'''}}）是一種含氮[[橋環(huán)化合物|橋環(huán)]]有機化合物。它主要因一類它的名為莨菪烷[[生物堿]]的[[衍生物]]而為人們所知，而這類生物堿包括了許多藥物，如[[阿托品]]和[[可卡因]]。這兩種生物堿都含有莨菪烷的衍生物[[托品酮]]。莨菪烷生物堿主要存在于[[古柯]]科植物（包括古柯）與茄科植物（包括曼德拉草、[[天仙子 (植物)|天仙子]]、[[顛茄]]、[[洋金花]]、[[馬鈴薯]]和[[番茄]]）之中。<ref>{{cite web | title=Atropine content of plants | work=USDA, ARS, National Genetic Resources Program. Phytochemical and Ethnobotanical Databases. <nowiki>[Online Database]</nowiki> National Germplasm Resources Laboratory, Beltsville, Maryland | url=http://sun.ars-grin.gov:8080/npgspub/xsql/duke/chemdisp.xsql?chemical=ATROPINE | accessdate=July 25, 2005}}</ref><ref>{{cite web | title=Cocaine content of plants | work=USDA, ARS, National Genetic Resources Program. Phytochemical and Ethnobotanical Databases. <nowiki>[Online Database]</nowiki> National Germplasm Resources Laboratory, Beltsville, Maryland | url=http://sun.ars-grin.gov:8080/npgspub/xsql/duke/chemdisp.xsql?chemical=COCAINE | accessdate=July 25, 2005}}</ref> 莨菪烷[[分子]]中的氮橋在1號碳和5號碳之間；盡管莨菪烷有兩個手性碳原子，但由于分子的對稱性，它并沒有[[光學活性]]。 8-氮雜雙環(huán)[3.2.1]辛烷（少了一個8位甲基的莨菪烷）被稱作降莨菪烷。 == 另見== * [[莨菪烷生物堿]] * [[阿托品]] * [[托品]] == 參考資料 == {{Reflist}} ==外部鏈接== * [http://tropane.lab-q.net/tropane-chemistry Tropane Chemistry]（英文） [[Category:莨菪烷| ]] ==參考來源== *[http://zh.wikipedia.org/wiki/%E8%8E%A8%E8%8F%AA%E7%83%B7 維基百科-莨菪烷]

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